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TU Dresden » Faculty of Mechanical Science and Engineering » Institute for Materials Science » Chair of Materials Science and Nanotechnology



Friday, 28 September 2007
(at 10:15 in room 115, Hallwachsstr. 3)
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Journal-Club
Electron induced ortho-meta isomerization of single molecules

Rafael Gutierrez

Institute for Materials Science
Dresden University of Technology
   






(From doi:10.1103/PhysRevLett.98.116102): A scanning tunneling microscope operating at 5 K is used to induce the isomerization of single chloronitrobenzene molecules on Cu(111) and verify the reaction. The threshold voltage of (227ü7) mV for this reaction is explained based on electron-induced vibrational heating. We propose that the isomerization is initiated by simultaneous excitation of two vibrational molecular modes via inelastically tunneling electrons. This excitation results in a shift of the distribution probability of chlorine and hydrogen positions, which facilitates their mutual exchange.



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Invited by G. Cuniberti (JClub)

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last modified: 2019.01.18 Fr
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