X-ray photoemission study of CeTIn5 (T = Co, Rh, Ir)
Journal of Physics Condensed Matter 26, 205601 (2014).
U. Treske, M. Samadi Khoshkhoo, F. Roth, M. Knupfer, E. D. Bauer, J. L. Sarrao, B. Büchner, and A. Koitzsch.
Journal DOI: https://doi.org/10.1088/0953-8984/26/20/205601

We investigated CeTIn5 (T = Co, Rh, Ir) using temperature- and angle-dependent x-ray photoemission spectroscopy. The Ce 3d core level has a very similar shape for all three materials and is indicative of weak f-hybridization. The spectra were analyzed using a simplified version of the Anderson impurity model, which yields a Ce 4f occupancy that is larger than 0.9. The temperature dependence shows a continuous, irreversible and exclusive broadening of the Ce 3d peaks, due to oxidation of Ce at the surface.

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X-ray photoemission study of CeTIn5 (T = Co, Rh, Ir)
Journal of Physics Condensed Matter 26, 205601 (2014).
U. Treske, M. Samadi Khoshkhoo, F. Roth, M. Knupfer, E. D. Bauer, J. L. Sarrao, B. Büchner, and A. Koitzsch.
Journal DOI: https://doi.org/10.1088/0953-8984/26/20/205601

We investigated CeTIn5 (T = Co, Rh, Ir) using temperature- and angle-dependent x-ray photoemission spectroscopy. The Ce 3d core level has a very similar shape for all three materials and is indicative of weak f-hybridization. The spectra were analyzed using a simplified version of the Anderson impurity model, which yields a Ce 4f occupancy that is larger than 0.9. The temperature dependence shows a continuous, irreversible and exclusive broadening of the Ce 3d peaks, due to oxidation of Ce at the surface.

Cover
©https://doi.org/10.1088/0953-8984/26/20/205601
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Involved Scientists